Un sistem optic în bandă largă, care poate identifica molecule în infraroșu la mijloc(A chip-scale broadband optical system that can sense molecules in the mid-infrared)

În acest studiu actual, cercetătorii s-au concentrat asupra gamei de infraroșii medii (IR), care, datorită absorbției lor moleculare puternice, este de obicei de 10 până la 1000 de ori mai mare decât cele din infraroșu vizibil sau aproape, este ideal pentru detectarea moleculelor de urme . Intervalul intermediar IR acoperă în mod eficient „amprenta” multor molecule.
Echipa a efectuat spectroscopia mid-IR dual-pieptene folosind două dispozitive nanophotonice de siliciu ca microresonatoare. Dispozitivele lor integrate au permis generarea directă a luminii infraroșii medii în bandă largă și viteze rapide de achiziție pentru caracterizarea absorbției moleculare

Posted: May 23, 2018

A chip-scale broadband optical system that can sense molecules in the mid-infrared

(Nanowerk News) Researchers at Columbia Engineering have demonstrated, for the first time, a chip-based dual-comb spectrometer in the mid-infrared range, that requires no moving parts and can acquire spectra in less than 2 microseconds. The system, which consists of two mutually coherent, low-noise, microresonator-based frequency combs spanning 2600 nm to 4100 nm, could lead to the development of a spectroscopy lab-on-a-chip for real-time sensing on the nanosecond time scale.
“Our results show the broadest optical bandwidth demonstrated for dual-comb spectroscopy on an integrated platform,” said Alexander Gaeta, David M. Rickey Professor of Applied Physics and of Materials Science and senior author of the study, published in Nature Communications(„Silicon-chip-based mid-infrared dual-comb spectroscopy”).
silicon microresonator generating a frequency comb
Schematic of silicon microresonator generating a frequency comb that samples molecules for chemical identification. (Image: Alexander Gaeta/Columbia Engineering)
Creating a spectroscopic sensing device on a chip that can realize real-time, high-throughput detection of trace molecules has been challenging. A few months ago, teams led by Gaeta and Michal Lipson, Higgins Professor of Electrical Engineering, were the first to miniaturize dual-frequency combs by putting two frequency comb generators on a single millimeter-sized chip. They have been working on broadening the frequency span of the dual combs, and on increasing the resolution of the spectrometer by tuning the lines of the comb.
In this current study, the researchers focused on the mid-infrared (mid-IR) range, which, because its strong molecular absorption is typically 10 to 1,000 times greater than those in the visible or near-infrared, is ideal for detecting trace molecules. The mid-IR range effectively covers the “fingerprint” of many molecules.
The team performed mid-IR dual-comb spectroscopy using two silicon nanophotonic devices as microresonators. Their integrated devices enabled the direct generation of broadband mid-infrared light and fast acquisition speeds for characterizing molecular absorption.
“Our work is a critical advance for chip-based dual-comb spectroscopy for liquid/solid phase studies,” said Mengjie Yu, lead author of the paper and a PhD student in Gaeta’s lab. “Our chip-scale broadband optical system, essentially a photonic lab-on-a-chip, is well-suited for identification of chemical species and could find a wide range of applications in chemistry, biomedicine, material science, and industrial process control.”
Source: Columbia University School of Engineering and Applied Science