Adăugarea filmelor subțiri CNT la țesături ar putea suporta electronice portabile(Addition of CNT thin-films to fabrics could power portable electronics)

Aceste două tipuri de materiale – numite p-type și picioare de tip n – sunt necesare pentru a genera suficientă putere într-un dispozitiv termoelectric. Polimerii polimerici, un alt material termoelectric organic studiat, produc în mod obișnuit materiale de tip n care funcționează mult mai rău decât omologii lor de tip p.
Faptul că filmele subțiri SWCNT pot face picioare de tip p și n de tip aceleași materiale cu performanțe identice înseamnă că curentul electric din fiecare picior este echilibrat în mod inerent, ceea ce ar trebui să simplifice fabricarea unui dispozitiv. Materialele cu cele mai performante performanțe au avut valori de performanță care depășesc materialele termoelectrice din materiale polimerice polimerice semiconductoare din materiale polimerice de ultimă oră.a declarat că introducerea SWCNT în țesături ar putea servi o funcție importantă pentru electronice personale „portabile”. Prin captarea căldurii corporale și transformarea acesteia în energie electrică, semiconductorul ar putea alimenta electronice portabile sau senzori încorporați în îmbrăcăminte.

Posted: Oct 31, 2017

Addition of CNT thin-films to fabrics could power portable electronics

(Nanowerk News) Scientists at the U.S. Department of Energy’s National Renewable Energy Laboratory (NREL) reported significant advances in the thermoelectric performance of organic semiconductors based on carbon nanotube thin films that could be integrated into fabrics to convert waste heat into electricity or serve as a small power source.
The research demonstrates significant potential for semiconducting single-walled carbon nanotubes (SWCNTs) as the primary material for efficient thermoelectric generators, rather than being used as a component in a “composite” thermoelectric material containing, for example, carbon nanotubes and a polymer. The discovery is outlined in Energy & Environmental Science(„Large n- and p-type thermoelectric power factors from doped semiconducting single-walled carbon nanotube thin films”).
Two men stand in front of a screen that shows carbon nanotubes
NREL scientists Andrew Ferguson, left, and Jeffrey Blackburn stand in front of a screen displaying single-walled carbon nanotubes. (Photo by Dennis Schroeder/NREL)
“There are some inherent advantages to doing things this way,” said Jeffrey Blackburn, a senior scientist in NREL’s Chemical and Materials Science and Technology center and co-lead author of the paper with Andrew Ferguson. These advantages include the promise of solution-processed semiconductors that are lightweight and flexible and inexpensive to manufacture. Other NREL authors are Bradley MacLeod, Rachelle Ihly, Zbyslaw Owczarczyk, and Katherine Hurst. The NREL authors also teamed with collaborators from the University of Denver and partners at International Thermodyne, Inc., based in Charlotte, N.C.
Ferguson, also a senior scientist in the Chemical and Materials Science and Technology center, said the introduction of SWCNT into fabrics could serve an important function for “wearable” personal electronics. By capturing body heat and converting it into electricity, the semiconductor could power portable electronics or sensors embedded in clothing.
Blackburn and Ferguson published two papers last year on SWCNTs, and the new research builds on their earlier work. The first paper, in Nature Energy („Tailored Semiconducting Carbon Nanotube Networks with Enhanced Thermoelectric Properties”), showed the potential that SWCNTs have for thermoelectric applications, but the films prepared in this study retained a large amount of insulating polymer. The second paper, in ACS Energy Letters („Polymer-Free Carbon Nanotube Thermoelectrics with Improved Charge Carrier Transport and Power Factor”), demonstrated that removing this “sorting” polymer from an exemplary SWNCT thin film improved thermoelectric properties.
The newest paper revealed that removing polymers from all SWCNT starting materials served to boost the thermoelectric performance and lead to improvements in how charge carriers move through the semiconductor. The paper also demonstrated that the same SWCNT thin film achieved identical performance when doped with either positive or negative charge carriers.
These two types of material–called the p-type and the n-type legs, respectively–are needed to generate sufficient power in a thermoelectric device. Semiconducting polymers, another heavily studied organic thermoelectric material, typically produce n-type materials that perform much worse than their p-type counterparts.
The fact that SWCNT thin films can make p-type and n-type legs out of the same material with identical performance means that the electrical current in each leg is inherently balanced, which should simplify the fabrication of a device. The highest performing materials had performance metrics that exceed current state-of-the-art solution-processed semiconducting polymer organic thermoelectrics materials.
“We could actually fabricate the device from a single material,” Ferguson said. “In traditional thermoelectric materials you have to take one piece that’s p-type and one piece that’s n-type and then assemble those into a device.”
Source: National Renewable Energy Laboratory